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2013


Hybrid nanocolloids with programmed three-dimensional shape and material composition
Hybrid nanocolloids with programmed three-dimensional shape and material composition

Mark, A. G., Gibbs, J. G., Lee, T., Fischer, P.

NATURE MATERIALS, 12(9):802-807, 2013, Max Planck Press Release. (article)

Abstract
Tuning the optical(1,2), electromagnetic(3,4) and mechanical properties of a material requires simultaneous control over its composition and shape(5). This is particularly challenging for complex structures at the nanoscale because surface-energy minimization generally causes small structures to be highly symmetric(5). Here we combine low-temperature shadow deposition with nanoscale patterning to realize nanocolloids with anisotropic three-dimensional shapes, feature sizes down to 20 nm and a wide choice of materials. We demonstrate the versatility of the fabrication scheme by growing three-dimensional hybrid nanostructures that contain several functional materials with the lowest possible symmetry, and by fabricating hundreds of billions of plasmonic nanohelices, which we use as chiral metafluids with record circular dichroism and tunable chiroptical properties.

Max Planck Press Release.

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Video - Fabrication of Designer Nanostructures DOI [BibTex]


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Self-Propelled Micromotors for Cleaning Polluted Watter

Soler, L., Magdanz, V., Fomin, V. M., Sanchez, S., Schmidt, O. G.

ACS Nano, 11, pages: 9611-9620, American Chemical Society, Washington, DC, 2013 (article)

Abstract
We describe the use of catalytically self-propelled microjets (dubbed micromotors) for degrading organic pollutants in water via the Fenton oxidation process. The tubular micromotors are composed of rolled-up functional nanomembranes consisting of Fe/Pt bilayers. The micromotors contain double functionality within their architecture, i.e., the inner Pt for the self-propulsion and the outer Fe for the in situ generation of ferrous ions boosting the remediation of contaminated water.The degradation of organic pollutants takes place in the presence of hydrogen peroxide, which acts as a reagent for the Fenton reaction and as main fuel to propel the micromotors. Factors influencing the efficiency of the Fenton oxidation process, including thickness of the Fe layer, pH, and concentration of hydrogen peroxide, are investigated. The ability of these catalytically self-propelled micromotors to improve intermixing in liquids results in the removal of organic pollutants ca. 12 times faster than when the Fenton oxidation process is carried out without catalytically active micromotors. The enhanced reaction\textendashdiffusion provided by micromotors has been theoretically modeled. The synergy between the internal and external functionalities of the micromotors, without the need of further functionalization, results into an enhanced degradation of nonbiodegradable and dangerous organic pollutants at small-scale environments and holds considerable promise for the remediation of contaminated water.

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DOI [BibTex]

DOI [BibTex]


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Stability of thin liquid films and sessile droplets under confinement

Dörfler, F., Rauscher, M., Dietrich, S.

Physical Review E, 88(1), American Physical Society, Melville, NY, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Nonequilibrium interfaces in colloidal fluids

Bier, M., Arnold, D.

Physical Review E, 88(6), American Physical Society, Melville, NY, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Colloidal particles at fluid interfaces: Effective interactions, dynamics and a gravitation\textendashlike instability

Bleibel, J., Dom\’\inguez, A., Oettel, M.

The European Physical Journal Special Topics, 222(11):3071-3087, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Anomalous transport in the crowded world of biological cells

Höfling, Felix, Franosch, Thomas

Reports on Progress in Physics, 76(4), IOP Pub., London, 2013, author: Höfling, Felix (article)

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link (url) DOI [BibTex]

link (url) DOI [BibTex]


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Flow pattern in the vicinity of self-propelling hot Janus particles

Bickel, T., Majee, A., Würger, A.

Physical Review E, 88(1), American Physical Society, Melville, NY, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


Chiral Colloidal Molecules And Observation of The Propeller Effect
Chiral Colloidal Molecules And Observation of The Propeller Effect

Schamel, D., Pfeifer, M., Gibbs, J. G., Miksch, B., Mark, A. G., Fischer, P.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 135(33):12353-12359, 2013 (article)

Abstract
Chiral molecules play an important role in biological and chemical processes, but physical effects due to their symmetry-breaking are generally weak. Several physical chiral separation schemes which could potentially be useful, including the propeller effect, have therefore not yet been demonstrated at the molecular scale. However, it has been proposed that complex nonspherical colloidal particles could act as ``colloidal molecules{''} in mesoscopic model systems to permit the visualization of molecular phenomena that are otherwise difficult to observe. Unfortunately, it is difficult to synthesize such colloids because surface minimization generally favors the growth of symmetric particles. Here we demonstrate the production of large numbers of complex colloids with glancing angle physical vapor deposition. We use chiral colloids to demonstrate the Baranova and Zel'dovich (Baranova, N. B.; Zel'dovich, B. Y. Chem. Phys. Lett. 1978, 57, 435) propeller effect: the separation of a racemic mixture by application of a rotating field that couples to the dipole moment of the enantiomers and screw propels them in opposite directions. The handedness of the colloidal suspensions is monitored with circular differential light scattering. An exact solution for the colloid's propulsion is derived, and comparisons between the colloidal system and the corresponding effect at the molecular scale are made.

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Video - Nanospropellers DOI [BibTex]

Video - Nanospropellers DOI [BibTex]


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Nonequilibrium Critical Casimir Effect in Binary Fluids

Furukawa, A., Gambassi, A., Dietrich, S., Tanaka, H.

Physical Review Letters, 111(5), American Physical Society, Woodbury, N.Y., 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Many-body effects for critical Casimir forces

Gomes de Mattos, T., Harnau, L., Dietrich, S.

The Journal of Chemical Physics, 138(7), 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Propulsion Mechanism of Catalytic Microjet Engines

Magdanz, V., Fomin, V. M., Soler, L., Sanchez, S., Schmidt, O. G., Hippler, M.

IEEE Transactions on Robotics and Automation, pages: 40-48, IEEE, New York, NY, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Impedance spectroscopy of ions at liquid-liquid interfaces

Bier, M., Reindl, A.

Physical Review E, 88(5), American Physical Society, Melville, NY, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Precursors of order in aggregates of patchy particles

Vasilyev, O., Klumov, B. A., Tkachenko, A. V.

Physical Review E, 88(1), American Physical Society, Melville, NY, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Two-temperature Langevin dynamics in a parabolic potential

Dotsenko, V., Maciolek, Anna, Vasilyev, O., Oshanin, G.

Physical Review E, 87(6), American Physical Society, Melville, NY, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


Indirect absorption spectroscopy using quantum cascade lasers: mid-infrared refractometry and photothermal spectroscopy
Indirect absorption spectroscopy using quantum cascade lasers: mid-infrared refractometry and photothermal spectroscopy

Pfeifer, M., Ruf, A., Fischer, P.

OPTICS EXPRESS, 21(22):25643-25654, 2013 (article)

Abstract
We record vibrational spectra with two indirect schemes that depend on the real part of the index of refraction: mid-infrared refractometry and photothermal spectroscopy. In the former, a quantum cascade laser (QCL) spot is imaged to determine the angles of total internal reflection, which yields the absorption line via a beam profile analysis. In the photothermal measurements, a tunable QCL excites vibrational resonances of a molecular monolayer, which heats the surrounding medium and changes its refractive index. This is observed with a probe laser in the visible. Sub-monolayer sensitivities are demonstrated. (C) 2013 Optical Society of America

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DOI [BibTex]


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Critical Casimir forces between homogeneous and chemically striped surfaces

Parisen Toldin, F., Tröndle, M., Dietrich, S.

Physical Review E, 88, American Physical Society, Melville, NY, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Comparison between theory and simulations for the magnetization and the susceptibility of polydisperse ferrofluids

Szalai, I., Nagy, S., Dietrich, S.

Journal of Physics: Condensed Matter, 25(46), IOP Pub., Bristol, UK, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Thermal activation of catalytic microjets in blood samples using microfluidic chips.

Soler, L., Mart\’\inez-Cisneros, C., Swiersy, A., Sanchez, S., Schmidt, O. G.

Lab on a Chip, 13, pages: 4299-4303, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Nematic liquid crystal boojums with handles on colloidal handlebodies

Liu, Q. K., Senyuk, B., Tasinkevych, M., Smalyukh, I. I.

Proceedings of the National Academy of Sciences of the United States of America, 110(23):9231-9236, National Academy of Sciences, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Critical Casimir torques and forces acting on needles in two spatial dimensions

Vasilyev, Oleg, Eisenriegler, E., Dietrich, Siegfried

Physical Review E, 88(1), American Physical Society, Melville, NY, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


Plasmonic nanohelix metamaterials with tailorable giant circular dichroism
Plasmonic nanohelix metamaterials with tailorable giant circular dichroism

Gibbs, J. G., Mark, A. G., Eslami, S., Fischer, P.

APPLIED PHYSICS LETTERS, 103(21), 2013, Featured cover article. (article)

Abstract
Plasmonic nanohelix arrays are shown to interact with electromagnetic fields in ways not typically seen with ordinary matter. Chiral metamaterials (CMMs) with feature sizes small with respect to the wavelength of visible light are a promising route to experimentally achieve such phenomena as negative refraction without the need for simultaneously negative e and mu. Here we not only show that giant circular dichroism in the visible is achievable with hexagonally arranged plasmonic nanohelix arrays, but that we can precisely tune the optical activity via morphology and lattice spacing. The discrete dipole approximation is implemented to support experimental data. (C) 2013 AIP Publishing LLC.

Featured cover article.

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DOI [BibTex]

DOI [BibTex]


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Critical Casimir forces along the isofields

Zubaszewska, M., Maciolek, A., Drzewinski, A.

Physical Review E, 88(5), American Physical Society, Melville, NY, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Surface states and the Casimir interaction in the Ising model

Abraham, D. B., Maciolek, A.

Europhysics letters, 101(2), Editrice Compositori., Bologna, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Crystallization, structural diversity, and anisotropy effects in 2D arrays of icosahedral viruses

Fukuto, M., Nguyen, Q. L., Vasilyev, O., Mank, N., Washington-Huges, C. L., Kuzmenko, I., Checco, A., Mao, Y., Wang, Q., Yang, L.

Soft Matter, 9(40):9633-9642, Royal Society of Chemistry, Cambridge, UK, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Dynamic arrest in model porous media-intermediate scattering functions

Spanner, Markus, Schnyder, Simon K., Höfling, Felix, Voigtmann, Thomas, Franosch, Thomas

Soft Matter, 9(5):1604-1611, Royal Society of Chemistry, Cambridge, UK, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Linear response relations in fluctuational electrodynamics

Golyk, V. A., Krüger, Matthias, Kardar, M.

Physical Review B, 88(15), American Physical Society, Woodbury, NY, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Ideal Polyethylene Nanocrystals

Osichov, A., Rabe, C., Vogtt, K., Narayanan, T., Harnau, Ludger, Drechsler, M., Ballauff, M.

Journal of the American Chemical Society, 135(31):11645-11650, American Chemical Society, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Self-Assembly of Two-Dimensional Colloidal Clusters by Tuning the Hydrophobicity, Composition, and Packing Geometry

Law, A. D., Auriol, M., Smith, D., Horozov, T. S., Buzza, D. M. A.

Physical Review Letters, 110, American Physical Society., Woodbury, N.Y., etc., 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Geometry-Induced Superdiffusion in Driven Crowded Systems

Bénichou, O., Bodrova, A., Chakraborty, D., Illien, P., Law, A. D., Mej\’\ia-Monasterio, C., Oshanin, G., Voituriez, R.

Physical Review Letters, 111(26), American Physical Society, Woodbury, N.Y., 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Overshoots in stress-strain curves: Colloid experiments and schematic mode coupling theory

Amann, Christian P, Siebenbürger, Miriam, Krüger, Matthias, Weysser, Fabian, Ballauff, Matthias, Fuchs, Matthias

Journal of Rheology, 57, pages: 149-175, 2013 (article)

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DOI [BibTex]

DOI [BibTex]


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Wetting in electrolyte solutions

Ibagon, Ingrid, Bier, Markus, Dietrich, Siegfried

The Journal of Chemical Physics, 138(21), American Institute of Physics, Woodbury, N.Y., 2013 (article)

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DOI [BibTex]

DOI [BibTex]

2009


Full phase and amplitude control in computer-generated holography
Full phase and amplitude control in computer-generated holography

Fratz, M., Fischer, P., Giel, D. M.

OPTICS LETTERS, 34(23):3659-3661, 2009 (article)

Abstract
We report what we believe to be the first realization of a computer-generated complex-valued hologram recorded in a single film of photoactive polymer. Complex-valued holograms give rise to a diffracted optical field with control over its amplitude and phase. The holograms are generated by a one-step direct laser writing process in which a spatial light modulator (SLM) is imaged onto a polymer film. Temporal modulation of the SLM during exposure controls both the strength of the induced birefringence and the orientation of the fast axis. We demonstrate that complex holograms can be used to impart arbitrary amplitude and phase profiles onto a beam and thereby open new possibilities in the control of optical beams. (C) 2009 Optical Society of America

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[BibTex]

2009


[BibTex]


Digital polarization holograms with defined magnitude and orientation of each pixel's birefringence
Digital polarization holograms with defined magnitude and orientation of each pixel’s birefringence

Fratz, M., Giel, D. M., Fischer, P.

OPTICS LETTERS, 34(8):1270-1272, 2009 (article)

Abstract
A new form of digital polarization holography is demonstrated that permits both the amplitude and the phase of a diffracted beam to be independently controlled. This permits two independent intensity images to be stored in the same hologram. To fabricate the holograms, a birefringence with defined retardance and orientation of the fast axis is recorded into a photopolymer film. The holograms are selectively read out by choosing the polarization state of the read beam. Polarization holograms of this kind increase the data density in holographic data storage and allow higher quality diffractive optical elements to be written. (C) 2009 Optical Society of America

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[BibTex]


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Interplay of complete wetting, critical adsorption, and capillary condensation

Drzewinski, A., Maciolek, A., Barasinski, A., Dietrich, S.

Physical Review E, 79, 2009 (article)

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DOI [BibTex]

DOI [BibTex]


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The critical Casimir effect: universal fluctuation-induced forces at work

Gambassi, A., Hertlein, C., Helden, L., Dietrich, S., Bechinger, C.

Europhysics News, 40(01):18-22, 2009 (article)

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DOI [BibTex]

DOI [BibTex]


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Effective interactions of colloids on nematic films

Oettel, M., Dominguez, A., Tasinkevych, M., Dietrich, S.

European Physical Journal E, 28(02):99-111, 2009 (article)

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DOI [BibTex]

DOI [BibTex]


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Self-diffusion and cooperative diffusion in semidilute polymer solutions as measured by fluorescence correlation spectroscopy

Zettl, U., Hoffmann, S. T., Koberling, F., Krausch, G., Enderlein, J., Harnau, L., Ballauff, M.

Macromolecules, 42, pages: 9537-9547, 2009 (article)

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DOI [BibTex]

DOI [BibTex]


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Free-energy function based on an all-atom model for proteins

Yoshidome, T., Oda, K., Harano, Y., Roth, R., Sugita, Y., Ikeguchi, M., Kinoshita, M.

Proteins: Structure, Function, and Bioinformatics, 77(4):950-961, 2009 (article)

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DOI [BibTex]

DOI [BibTex]


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On scale-free and poly-scale behaviors of random hierarchical networks

Avetisov, V. A., Chertovitch, A. V., Nechaev, S .K., Vasilyev, O. A.

Journal of Statistical Mechanics: Theory and Experiment, July 2009, 2009 (article)

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DOI [BibTex]

DOI [BibTex]


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3D Brownian diffusion of submicron-sized particle clusters

Hoffmann, M., Wagner, C. S., Harnau, L., Wittemann, A.

ACS Nano, 3(10):3326-3334, 2009 (article)

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DOI [BibTex]

DOI [BibTex]


Controlled Propulsion of Artificial Magnetic Nanostructured Propellers
Controlled Propulsion of Artificial Magnetic Nanostructured Propellers

Ghosh, A., Fischer, P.

NANO LETTERS, 9(6):2243-2245, 2009, Featured highlight ‘Nanotechnology: The helix that delivers’ Nature 459, 13 (2009). (article)

Abstract
For biomedical applications, such as targeted drug delivery and microsurgery, it is essential to develop a system of swimmers that can be propelled wirelessly in fluidic environments with good control. Here, we report the construction and operation of chiral colloidal propellers that can be navigated in water with micrometer-level precision using homogeneous magnetic fields. The propellers are made via nanostructured surfaces and can be produced in large numbers. The nanopropellers can carry chemicals, push loads, and act as local probes in rheological measurements.

Featured highlight ‘Nanotechnology: The helix that delivers’ Nature 459, 13 (2009).

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Video - Nanospropellers DOI [BibTex]

Video - Nanospropellers DOI [BibTex]


Absolute Asymmetric Reduction Based on the Relative Orientation of Achiral Reactants
Absolute Asymmetric Reduction Based on the Relative Orientation of Achiral Reactants

Kuhn, A., Fischer, P.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 48(37):6857-6860, 2009 (article)

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DOI [BibTex]

DOI [BibTex]


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Normal and lateral critical Casimir forces between colloids and patterned substrates

Tröndle, M., Kondrat, S., Gambassi, A., Harnau, L., Dietrich, S.

EPL, 88, 2009 (article)

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DOI [BibTex]


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Critical wetting transitions in two-dimensional systems subject to long-ranged boundary fields

Drzewinski, A., Maciolek, A., Barasinski, A., Dietrich, S.

Physical Review E, 79, 2009 (article)

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DOI [BibTex]


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Derivation of a non-local interfacial model for 3D wetting in an external field

Bernardino, N. R., Parry, A. O., Rascon, C., Romero-Enrique, J. M.

Journal of Physics: Condensed Matter, 21(46), 2009 (article)

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DOI [BibTex]

DOI [BibTex]


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Coupling of rotational motion with shape fluctuations of core-shell microgels having tunable softness

Bolisetty, S., Hoffmann, M., Lekkala, S., Hellweg, T., Ballauff, M., Harnau, L.

Macromolecules, 42, pages: 1264-1269, 2009 (article)

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DOI [BibTex]

DOI [BibTex]


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Strong-disorder paramagnetic-ferromagnetic fixed point in the square-lattice +/-J Ising model

Parisen Toldin, F., Pelissetto, A., Vicari, E.

Journal of Statistical Physics, 135(5):1039-1061, 2009 (article)

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DOI [BibTex]

DOI [BibTex]


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Structure and interaction of flexible dendrimers in concentrated solution

Rosenfeldt, S., Ballauff, M., Lindner, P., Harnau, L.

The Journal of Chemical Physics, 130, 2009 (article)

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DOI [BibTex]

DOI [BibTex]


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Layering of (BMIM)+-based ionic liquids at a charged sapphire interface

Mezger, M., Schramm, S., Schröder, H., Reichert, H., Deutsch, M., de Souza, E. J., Okasinski, J. S., Ocko, B. M., Honkimäki, V., Dosch, H.

Journal of Chemical Physics, 131, 2009 (article)

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DOI [BibTex]

DOI [BibTex]