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2013


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Hybrid nanocolloids with programmed three-dimensional shape and material composition

Mark, A. G., Gibbs, J. G., Lee, T., Fischer, P.

NATURE MATERIALS, 12(9):802-807, 2013, Max Planck Press Release. (article)

Abstract
Tuning the optical(1,2), electromagnetic(3,4) and mechanical properties of a material requires simultaneous control over its composition and shape(5). This is particularly challenging for complex structures at the nanoscale because surface-energy minimization generally causes small structures to be highly symmetric(5). Here we combine low-temperature shadow deposition with nanoscale patterning to realize nanocolloids with anisotropic three-dimensional shapes, feature sizes down to 20 nm and a wide choice of materials. We demonstrate the versatility of the fabrication scheme by growing three-dimensional hybrid nanostructures that contain several functional materials with the lowest possible symmetry, and by fabricating hundreds of billions of plasmonic nanohelices, which we use as chiral metafluids with record circular dichroism and tunable chiroptical properties.

Max Planck Press Release.

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Video - Fabrication of Designer Nanostructures DOI [BibTex]


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Chiral Colloidal Molecules And Observation of The Propeller Effect

Schamel, D., Pfeifer, M., Gibbs, J. G., Miksch, B., Mark, A. G., Fischer, P.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 135(33):12353-12359, 2013 (article)

Abstract
Chiral molecules play an important role in biological and chemical processes, but physical effects due to their symmetry-breaking are generally weak. Several physical chiral separation schemes which could potentially be useful, including the propeller effect, have therefore not yet been demonstrated at the molecular scale. However, it has been proposed that complex nonspherical colloidal particles could act as ``colloidal molecules{''} in mesoscopic model systems to permit the visualization of molecular phenomena that are otherwise difficult to observe. Unfortunately, it is difficult to synthesize such colloids because surface minimization generally favors the growth of symmetric particles. Here we demonstrate the production of large numbers of complex colloids with glancing angle physical vapor deposition. We use chiral colloids to demonstrate the Baranova and Zel'dovich (Baranova, N. B.; Zel'dovich, B. Y. Chem. Phys. Lett. 1978, 57, 435) propeller effect: the separation of a racemic mixture by application of a rotating field that couples to the dipole moment of the enantiomers and screw propels them in opposite directions. The handedness of the colloidal suspensions is monitored with circular differential light scattering. An exact solution for the colloid's propulsion is derived, and comparisons between the colloidal system and the corresponding effect at the molecular scale are made.

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Video - Nanospropellers DOI [BibTex]

Video - Nanospropellers DOI [BibTex]


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Indirect absorption spectroscopy using quantum cascade lasers: mid-infrared refractometry and photothermal spectroscopy

Pfeifer, M., Ruf, A., Fischer, P.

OPTICS EXPRESS, 21(22):25643-25654, 2013 (article)

Abstract
We record vibrational spectra with two indirect schemes that depend on the real part of the index of refraction: mid-infrared refractometry and photothermal spectroscopy. In the former, a quantum cascade laser (QCL) spot is imaged to determine the angles of total internal reflection, which yields the absorption line via a beam profile analysis. In the photothermal measurements, a tunable QCL excites vibrational resonances of a molecular monolayer, which heats the surrounding medium and changes its refractive index. This is observed with a probe laser in the visible. Sub-monolayer sensitivities are demonstrated. (C) 2013 Optical Society of America

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DOI [BibTex]


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Plasmonic nanohelix metamaterials with tailorable giant circular dichroism

Gibbs, J. G., Mark, A. G., Eslami, S., Fischer, P.

APPLIED PHYSICS LETTERS, 103(21), 2013, Featured cover article. (article)

Abstract
Plasmonic nanohelix arrays are shown to interact with electromagnetic fields in ways not typically seen with ordinary matter. Chiral metamaterials (CMMs) with feature sizes small with respect to the wavelength of visible light are a promising route to experimentally achieve such phenomena as negative refraction without the need for simultaneously negative e and mu. Here we not only show that giant circular dichroism in the visible is achievable with hexagonally arranged plasmonic nanohelix arrays, but that we can precisely tune the optical activity via morphology and lattice spacing. The discrete dipole approximation is implemented to support experimental data. (C) 2013 AIP Publishing LLC.

Featured cover article.

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DOI [BibTex]

DOI [BibTex]


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Two-dimensional magnetic micro-module reconfigurations based on inter-modular interactions

Miyashita, S., Diller, E., Sitti, M.

The International Journal of Robotics Research, 32(5):591-613, SAGE Publications Sage UK: London, England, 2013 (article)

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[BibTex]

[BibTex]


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Contact compliance effects in the frictional response of bioinspired fibrillar adhesives

Piccardo, M., Chateauminois, A., Fretigny, C., Pugno, N. M., Sitti, M.

Journal of The Royal Society Interface, 10(83):20130182, The Royal Society, 2013 (article)

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Project Page [BibTex]

Project Page [BibTex]


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Co-chairs

VINCENT, Julian, ZHU, Di, DAI, Zhendong, CHEN, Da, JIANG, Lei, KANG, Le, REN, Luquan, XUE, Qunji, Zhao, Chunsheng, BARNES, Jon, others

2013 (article)

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[BibTex]

[BibTex]


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Topological Control of Cell Sheet Migration by the 3D Microenvironment

Song, J., Kim, Y. T., Hazar, M., LeDuc, P. R., Davidson, L. A., Sitti, M.

Biophysical Journal, 104(2):147a, Elsevier, 2013 (article)

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[BibTex]

[BibTex]


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Independent control of multiple magnetic microrobots in three dimensions

Diller, E., Giltinan, J., Sitti, M.

The International Journal of Robotics Research, 32(5):614-631, SAGE Publications Sage UK: London, England, 2013 (article)

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[BibTex]

[BibTex]


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Modular micro-robotic assembly through magnetic actuation and thermal bonding

Diller, E., Zhang, N., Sitti, M.

Journal of Micro-Bio Robotics, 8(3-4):121-131, Springer Berlin Heidelberg, 2013 (article)

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[BibTex]

[BibTex]


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A simulation and design tool for a passive rotation flapping wing mechanism

Arabagi, V., Hines, L., Sitti, M.

IEEE/ASME Transactions on Mechatronics, 18(2):787-798, 2013 (article)

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Project Page [BibTex]

Project Page [BibTex]


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GECKO-INSPIRED POLYMER ADHESIVES

Menguc, Yigit, Metin, Metin

Polymer Adhesion, Friction, and Lubrication, pages: 351, Wiley, 2013 (article)

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[BibTex]

[BibTex]


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Near and far-wall effects on the three-dimensional motion of bacteria-driven microbeads

Edwards, M. R., Wright Carlsen, R., Sitti, M.

Applied Physics Letters, 102(14):143701, AIP, 2013 (article)

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Project Page [BibTex]

Project Page [BibTex]


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Magnetically Actuated Soft Capsule With the Multimodal Drug Release Function

Yim, S., Goyal, K., Sitti, M.

IEEE/ASME Trans. on Mechatronics, 18(4):1413-1418, IEEE, 2013 (article)

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Project Page [BibTex]

Project Page [BibTex]


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Tank-like module-based climbing robot using passive compliant joints

Seo, T., Sitti, M.

IEEE/ASME Transactions on Mechatronics, 18(1):397-408, 2013 (article)

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[BibTex]

[BibTex]


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Enhanced fabrication and characterization of gecko-inspired mushroom-tipped microfiber adhesives

Song, J., Mengüç, Y., Sitti, M.

Journal of Adhesion Science and Technology, 27(17):1921-1932, Routledge, 2013 (article)

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Project Page [BibTex]

Project Page [BibTex]


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Micro-scale mobile robotics

Diller, E., Sitti, M.

Foundations and Trends in Robotics, 2(3):143-259, Now Publishers Incorporated, 2013 (article)

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[BibTex]

[BibTex]


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Survey and Introduction to the Focused Section on Bio-Inspired Mechatronics

Sitti, M., Menciassi, A., Ijspeert, A., Low, K. H., Kim, S.

Mechatronics, IEEE/ASME Transactions on, 18(2):409-418, DOI: 10.1109/TMECH.2012. 2233492, 2013 (article)

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[BibTex]

[BibTex]

2011


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Quantum-Cascade Laser-Based Vibrational Circular Dichroism

Luedeke, S., Pfeifer, M., Fischer, P.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133(15):5704-5707, 2011 (article)

Abstract
Vibrational circular dichroism (VCD) spectra were recorded with a tunable external-cavity quantum-cascade laser (QCL). In comparison with standard thermal light sources in the IR, QCLs provide orders of magnitude more power and are therefore promising for VCD studies in strongly absorbing solvents. The brightness of this novel light source is demonstrated with VCD and IR absorption measurements of a number of compounds, including proline in water.

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DOI [BibTex]

2011


DOI [BibTex]


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Actively coupled cavity ringdown spectroscopy with low-power broadband sources

Petermann, C., Fischer, P.

OPTICS EXPRESS, 19(11):10164-10173, 2011 (article)

Abstract
We demonstrate a coupling scheme for cavity enhanced absorption spectroscopy that makes use of an intracavity acousto-optical modulator to actively switch light into (and out of) a resonator. This allows cavity ringdown spectroscopy (CRDS) to be implemented with broadband nonlaser light sources with spectral power densities of less than 30 mu W/nm. Although the acousto-optical element reduces the ultimate detection limit by introducing additional losses, it permits absorptivities to be measured with a high dynamic range, especially in lossy environments. Absorption measurements for the forbidden transition of gaseous oxygen in air at similar to 760nm are presented using a low-coherence cw-superluminescent diode. The same setup was electronically configured to cover absorption losses from 1.8 x 10(-8)cm(-1) to 7.5\% per roundtrip. This could be of interest in process analytical applications. (C) 2011 Optical Society of America

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DOI [BibTex]

DOI [BibTex]


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Magnetically actuated propulsion at low Reynolds numbers: towards nanoscale control

Fischer, P., Ghosh, A.

NANOSCALE, 3(2):557-563, 2011 (article)

Abstract
Significant progress has been made in the fabrication of micron and sub-micron structures whose motion can be controlled in liquids under ambient conditions. The aim of many of these engineering endeavors is to be able to build and propel an artificial micro-structure that rivals the versatility of biological swimmers of similar size, e. g. motile bacterial cells. Applications for such artificial ``micro-bots'' are envisioned to range from microrheology to targeted drug delivery and microsurgery, and require full motion-control under ambient conditions. In this Mini-Review we discuss the construction, actuation, and operation of several devices that have recently been reported, especially systems that can be controlled by and propelled with homogenous magnetic fields. We describe the fabrication and associated experimental challenges and discuss potential applications.

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Video - Nanospropellers DOI [BibTex]


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Design and application of a wire-driven bidirectional telescopic mechanism for workspace expansion with a focus on shipbuilding tasks

Lee, D., Chang, D., Shin, Y., Son, D., Kim, T., Lee, K., Kim, J.

Advanced Robotics, 25, 2011 (article)

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[BibTex]

[BibTex]


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Weak value amplified optical activity measurements

Pfeifer, M., Fischer, P.

Opt. Express, 19(17):16508-16517, OSA, 2011 (article)

Abstract
We present a new form of optical activity measurement based on a modified weak value amplification scheme. It has recently been shown experimentally that the left- and right-circular polarization components refract with slightly different angles of refraction at a chiral interface causing a linearly polarized light beam to split into two. By introducing a polarization modulation that does not give rise to a change in the optical rotation it is possible to differentiate between the two circular polarization components even after post-selection with a linear polarizer. We show that such a modified weak value amplification measurement permits the sign of the splitting and thus the handedness of the optically active medium to be determined. Angular beam separations of Δθ ∼ 1 nanoradian, which corresponds to a circular birefringence of Δn ∼ 1 × 10−9, could be measured with a relative error of less than 1%.

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link (url) DOI [BibTex]

link (url) DOI [BibTex]


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Waalbot II: Adhesion recovery and improved performance of a climbing robot using fibrillar adhesives

Murphy, M. P., Kute, C., Mengüç, Y., Sitti, M.

The International Journal of Robotics Research, 30(1):118-133, SAGE Publications Sage UK: London, England, 2011 (article)

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Project Page [BibTex]

Project Page [BibTex]


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Automated 2-D nanoparticle manipulation using atomic force microscopy

Onal, C. D., Ozcan, O., Sitti, M.

IEEE Transactions on Nanotechnology, 10(3):472-481, IEEE, 2011 (article)

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[BibTex]

[BibTex]


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Biaxial mechanical modeling of the small intestine

Bellini, C., Glass, P., Sitti, M., Di Martino, E. S.

Journal of the mechanical behavior of biomedical materials, 4(8):1727-1740, Elsevier, 2011 (article)

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Project Page [BibTex]

Project Page [BibTex]


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Assembly and disassembly of magnetic mobile micro-robots towards deterministic 2-D reconfigurable micro-systems

Diller, E., Pawashe, C., Floyd, S., Sitti, M.

The International Journal of Robotics Research, 30(14):1667-1680, SAGE Publications Sage UK: London, England, 2011 (article)

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[BibTex]

[BibTex]


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Modeling of stochastic motion of bacteria propelled spherical microbeads

Arabagi, V., Behkam, B., Cheung, E., Sitti, M.

Journal of Applied Physics, 109(11):114702, AIP, 2011 (article)

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Project Page [BibTex]

Project Page [BibTex]


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The effect of aspect ratio on adhesion and stiffness for soft elastic fibres

Aksak, B., Hui, C., Sitti, M.

Journal of The Royal Society Interface, 8(61):1166-1175, The Royal Society, 2011 (article)

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Project Page [BibTex]

Project Page [BibTex]


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Enhancing adhesion of biologically inspired polymer microfibers with a viscous oil coating

Cheung, E., Sitti, M.

The Journal of Adhesion, 87(6):547-557, Taylor & Francis Group, 2011 (article)

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Project Page [BibTex]

Project Page [BibTex]


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Piezoelectric polymer fiber arrays for tactile sensing applications

Sümer, B., Aksak, B., Şsahin, K., Chuengsatiansup, K., Sitti, M.

Sensor Letters, 9(2):457-463, American Scientific Publishers, 2011 (article)

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Project Page [BibTex]

Project Page [BibTex]


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Control methodologies for a heterogeneous group of untethered magnetic micro-robots

Floyd, S., Diller, E., Pawashe, C., Sitti, M.

The International Journal of Robotics Research, 30(13):1553-1565, SAGE Publications, 2011 (article)

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[BibTex]

[BibTex]

2008


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Voltage-Controllable Magnetic Composite Based on Multifunctional Polyethylene Microparticles

Ghosh, A., Sheridon, N. K., Fischer, P.

SMALL, 4(11):1956-1958, 2008 (article)

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DOI [BibTex]

2008



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ENHANCED ADHESION OF PDMS SURFACES FUNCTIONALIZED BY POLY (n-BUTYL ACRYLATE) BRUSHES INSPIRED BY GECKO FOOT HAIRS

Nese, A., Lee, H., Dong, H., Aksak, B., Cusick, B., Kowalewski, T., Matyjaszewski, K., Sitti, M.

Polymer Preprints, 49(2):107, 2008 (article)

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[BibTex]

[BibTex]


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Design and development of the lifting and propulsion mechanism for a biologically inspired water runner robot

Floyd, S., Sitti, M.

IEEE transactions on robotics, 24(3):698-709, IEEE, 2008 (article)

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[BibTex]

[BibTex]


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Control of Cell Behavior by Aligned Micro/Nanofibrous Biomaterial Scaffolds Fabricated by Spinneret-Based Tunable Engineered Parameters (STEP) Technique

Nain, A. S., Phillippi, J. A., Sitti, M., MacKrell, J., Campbell, P. G., Amon, C.

Small, 4(8):1153-1159, Wiley Online Library, 2008 (article)

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[BibTex]

[BibTex]


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Rolling and spinning friction characterization of fine particles using lateral force microscopy based contact pushing

Sümer, B., Sitti, M.

Journal of Adhesion Science and Technology, 22(5-6):481-506, Taylor & Francis Group, 2008 (article)

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[BibTex]

[BibTex]


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Modeling the soft backing layer thickness effect on adhesion of elastic microfiber arrays

Long, R., Hui, C., Kim, S., Sitti, M.

Journal of Applied Physics, 104(4):044301, AIP, 2008 (article)

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Project Page [BibTex]

Project Page [BibTex]


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Cross-talk compensation in atomic force microscopy

Onal, C. D., Sümer, B., Sitti, M.

Review of scientific instruments, 79(10):103706, AIP, 2008 (article)

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[BibTex]

[BibTex]


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Adhesion of biologically inspired oil-coated polymer micropillars

Cheung, E., Sitti, M.

Journal of Adhesion Science and Technology, 22(5-6):569-589, Taylor & Francis Group, 2008 (article)

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[BibTex]

[BibTex]


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Vision-based feedback strategy for controlled pushing of microparticles

Lynch, N. A., Onal, C. D., Schuster, E., Sitti, M.

Journal of Micro-Nano Mechatronics, 4(1-2):73-83, Springer-Verlag, 2008 (article)

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[BibTex]

[BibTex]


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Effect of quantity and configuration of attached bacteria on bacterial propulsion of microbeads

Behkam, B., Sitti, M.

Applied Physics Letters, 93(22):223901, AIP, 2008 (article)

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[BibTex]

[BibTex]


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Preface to the Journal of Micro-Nano Mechatronics

Dario, P., Fukuda, T., Sitti, M.

Journal of Micro-Nano Mechatronics, 4(1-2):1-1, Springer-Verlag, 2008 (article)

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[BibTex]

[BibTex]


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A legged anchoring mechanism for capsule endoscopes using micropatterned adhesives

Glass, P., Cheung, E., Sitti, M.

IEEE Transactions on Biomedical Engineering, 55(12):2759-2767, IEEE, 2008 (article)

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Project Page [BibTex]

Project Page [BibTex]


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Dynamic modeling of stick slip motion in an untethered magnetic microrobot

Pawashe, C., Floyd, S., Sitti, M.

Proceedings of Robotics: Science and Systems IV, Zurich, Switzerland, 2008 (article)

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[BibTex]

[BibTex]

2005


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Nonlinear optical spectroscopy of chiral molecules

Fischer, P., Hache, F.

CHIRALITY, 17(8):421-437, 2005 (article)

Abstract
We review nonlinear optical processes that are specific to chiral molecules in solution and on surfaces. In contrast to conventional natural optical activity phenomena, which depend linearly on the electric field strength of the optical field, we discuss how optical processes that are nonlinear (quadratic, cubic, and quartic) functions of the electromagnetic field strength may probe optically active centers and chiral vibrations. We show that nonlinear techniques open entirely new ways of exploring chirality in chemical and biological systems: The cubic processes give rise to nonlinear circular dichroism and nonlinear optical rotation and make it possible to observe dynamic chiral processes at ultrafast time scales. The quadratic second-harmonic and sum-frequency-generation phenomena and the quartic processes may arise entirely in the electric-dipole approximation and do not require the use of circularly polarized light to detect chirality: They provide surface selectivity and their observables can be relatively much larger than in linear optical activity. These processes also give rise to the generation of light at a new color, and in liquids this frequency conversion only occurs if the solution is optically active. We survey recent chiral nonlinear optical experiments and give examples of their application to problems of biophysical interest. (C) 2005 Wiley-Liss, Inc.

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DOI [BibTex]

2005


DOI [BibTex]


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Negative refraction at optical frequencies in nonmagnetic two-component molecular media

Chen, Y., Fischer, P., Wise, F.

PHYSICAL REVIEW LETTERS, 95(6), 2005 (article)

Abstract
There is significant motivation to develop media with negative refractive indices at optical frequencies, but efforts in this direction are hampered by the weakness of the magnetic response at such frequencies. We show theoretically that a nonmagnetic medium with two atomic or molecular constituents can exhibit a negative refractive index. A negative index is possible even when the real parts of both the permittivity and permeability are positive. This surprising result provides a route to isotropic negative-index media at optical frequencies.

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DOI [BibTex]

DOI [BibTex]